Aplikasi penggunaan Mono Di-Acyl Glycerol (MDAG) untuk meningkatkan stabilitas dan titik leleh dark chocolate [Application of Mono Di-Acyl Glycerol (MDAG) to Improve Stability and Melting Point of Dark Chocolate]
DOI:
https://doi.org/10.23960/jtihp.v27i1.53-60
Keywords:
cocoa butter, dark chocolate, MDAG, melting pointAbstract
Chocolate is one of the processed cocoa products in the form of a water-in-oil (w/o) emulsion. In its production, cocoa powder, sugar, and vanilla are evenly dispersed in cocoa butter by using lecithin as an emulsifier. Lecithin is an effective emulsifier used to w/o emulsions due to its HLB ranging (4-6). So far, by using a single emulsifier (lecithin), it will takes 8-12 hours of conching to produce dark chocolate with good quality and stability. Hence, the addition of MDAG which has an HLB ranging 3-5 as a co-emulsifier, is expected to reduce conching time and increase product stability and melting point. The study was aimed to determine the effect of adding MDAG as a co-emulsifier to increase the stability and melting point of dark chocolate and to determine the optimum concentration of MDAG addition. The study was arranged in a completely randomized design (CRD), the treatments were 6 levels of lecithin/MDAG ratio (%) in the dough, namely P0 (0.60:0), P1 (0.56:0.04), P2 (0.52 :0.08), P3 (0.48:0.12), P4 (0.44:0.16), and P5 (0.40:0.20). Each treatment level was repeated 3 times to obtain 18 experimental units. The parameters tested were melting point and fat-blooming. To see whether there was an effect of adding MDAG as a co-emulsifier, the data obtained were analyzed using ANOVA and followed by DNMRT at a 5% significance level. The results showed that the addition of MDAG as a co-emulsifier could increase the stability and melting point of dark chocolate. The best proportion of emulsifier mixture of lecithin and MDAG is the use of 0.44% lecithin and 0.16% MDAG which produces a melting point of 34oCwith a level of stability during storage at room temperature was quite high (not having fat-bloomduring storage up to 21 days).
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References
Afoakwa, E. O. (2016). Chocolate Science and Technology: Second Edition. In Chocolate Science and Technology: Second Edition,87: 181-190. https://doi.org/10.1002/9781118913758
Arif, M., Tamrin, & Syukri. (2017). Pengaruh penambahan karagenan dan jahe terhadap organoleptik dan sifat fisikokimia cokelat batang. Jurnal Sains Dan Teknologi Pangan,2(2): 394-404.
Ariyanti, M., Ramlah, S., & Yumas, M. (2019). Pengaruh lama fermentasi dan pengepresan berulang terhadap mutu bubuk kakao. Jurnal Industri Hasil Perkebunan,1(14): 21-27.https://doi.org/10.33104/jihp.v14i1.4849
Bahari, A., & Akoh, C. C. (2018). Texture, rheology and fat bloom study of ‘chocolates’ made from cocoa butter equivalent synthesized from illipe butter and palm mid-fraction. LWT, 249-354. https://doi.org/10.1016/j.lwt.2018.07.013
Bahramparvar, M., & Tehrani, M. M. (2011). Application and functions of stabilizers in ice cream. In Food Reviews International, 27(4):389-407. https://doi.org/10.1080/87559129.2011.563399
Beckett, S. T. (2009). Industrial Chocolate Manufacture and Use: Fourth Edition. In Industrial Chocolate Manufacture and Use: Fourth Edition. https://doi.org/10.1002/9781444301588
Briones, V., & Aguilera, J. M. (2005). Image analysis of changes in surface color of chocolate. Food Research International, 38: 87–94. https://doi.org/10.1016/j.foodres.2004.09.002
Buscato, M. H. M., Hara, L. M., Bonomi, É. C., Calligaris, G. de A., Cardoso, L. P., Grimaldi, R., & Kieckbusch, T. G. (2018). Delaying fat bloom formation in dark chocolate by adding sorbitan monostearate or cocoa butter stearin. Food Chemistry, 256: 390-393. https://doi.org/10.1016/j.foodchem.2018.02.127
Delbaere, C., Van de Walle, D., Depypere, F., Gellynck, X., & Dewettinck, K. (2016). Relationship between chocolate microstructure, oil migration, and fat bloom in filled chocolates. In European Journal of Lipid Science and Technology, 18(12). p.1800-1826. https://doi.org/10.1002/ejlt.201600164
Deliana, D., Susilo, B., &, & Yulianingsih, R. (2014). Analisa karakteristik fisik dan sensorik permen cokelat dari komposisi bubuk bungkil kacang tanah dan variasi konsentrasi tepung porang (Amorphophallus oncophyllus). Jurnal Bioproses Komoditas Tropis,2(1), 62–71. https://jbkt.ub.ac.id/index.php/jbkt/article/download/138/128
Dias, J., Alvarenga, N., & Sousa, I. (2017). Shelf-life of reduced-fat white chocolate fillings using iota-carrageenan. Emirates Journal of Food and Agriculture, 29(11):893-898. https://doi.org/10.9755/ejfa.2017.v29.i11.1498
Ekantari, N., Budhiyanti, S. A., Fitriya, W., Hamdan, A. B., & Riaty, C. (2019). Stability of chocolate bars fortified with nanocapsules carotenoid of Spirulina platensis. IOP Conference Series: Earth and Environmental Science, 370: 1-14.https://doi.org/10.1088/1755-1315/370/1/012079
Ferdiansyah, M. K. (2019).Pengaruh hidrokoloid pada mutu produk bakeri. Agrisaintifika: Jurnal Ilmu-Ilmu Pertanian, 2(2), 101-107. https://doi.org/10.32585/ags.v2i2.259
Hasibuan, H. A., Ijah, , & Hardika, A. P. (2015). Palm based mono-diacylglyceride as an emulsifier in producing chocolate with cocoa butter substitute. Pelita Perkebunan (a Coffee and Cocoa Research Journal), 31(2), 109-118.doi.org/10.22302/iccri.jur.pelitaperkebunan.v31i2.166
Hasibuan, H. A., & Siahaan, D. (2013). Determination of iodine value and melting point based on solid fat content of palm oil and palm kernel oil (Comparison with AOCS standard method). Jurnal Standardisasi, 15(1) 47-57.
Hernani, N., Mulyono, E., & Ramadhan, K. (2017). Pemanfaatan monodiasilgliserol (MDAG) hasil sintesa dari butter biji pala dan gliserol sebagai emulsifier pada kualitas produk sosis ayam. Jurnal Penelitian Pascapanen Pertanian, 13(1):74–81. https://doi.org/10.21082/jpasca.v13n2.2016.74-82
Jin, J., & Hartel, R. W. (2020). Accelerated fat bloom in chocolate model systems: replacement of cocoa powder with sugar particles and the effects of lecithin. JAOCS, Journal of the American Oil Chemists’ Society, 1-12. https://doi.org/10.1002/aocs.12345
Lonchampt, P., & Hartel, R. W. (2004). Fat bloom in chocolate and compound coatings. In European Journal of Lipid Science and Technology, 106 (4):241-274. https://doi.org/10.1002/ejlt.200400938
Masykuri, Nurwantoro, A., & Wibawa, R. A. (2009). Pengaruh penggunaan karaginan sebagai penstabil terhadap kondisi fisik dan tingkat kesukaan pada es krim coklat. Seminar Nasional Kebangkitan Peternakan, Semarang 20 Mei 2009, 503-509.
Moonen, H., & Bas, H. (2015). Mono- and Diglycerides. In Emulsifiers in Food Technology: Second Edition. https://doi.org/10.1002/9781118921265.ch4
Nurhafsah, Hatta Herman, P. P. (2020). pengaruh penggunaan nib kakao fermentasi terhadap sifat fisikokimia coklat. Jurnal Pengkajian Dan Pengembangan Teknologi Pertanian, 23(1), 129–139. http://ejurnal.litbang.pertanian.go.id/index.php/jpengkajian/article/download/10165/9244
Quevedo, R., Valencia, E., Alvarado, F., Ronceros, B., & Bastias, J. M. (2013). Comparison of whiteness index vs. fractal fourier in the determination of bloom chocolate using image analysis. Food and Bioprocess Technology, 6:1878–1884. https://doi.org/10.1007/s11947-011-0729-x
Ramlah, S., & Sampe Barra, A. L. (2018). Karakteristik dan citarasa cokelat putih dari lemak kakao non deodorisasi dan deodorisasi. Jurnal Industri Hasil Perkebunan, 13(2): 117-128. https://doi.org/10.33104/jihp.v13i2.4188
Sato, S., Hondoh, H., & Ueno, S. (2021). Fat bloom caused by partial de-oiling on chocolate surfaces after high-temperature exposure. JAOCS, Journal of the American Oil Chemists’ Society. https://doi.org/10.1002/aocs.12447
Stortz, T. A., & Marangoni, A. G. (2011). Heat resistant chocolate. In Trends in Food Science and Technology, . 22: 201-214. https://doi.org/10.1016/j.tifs.2011.02.001
Subroto, E. (2020). Monoacylglycerols and diacylglycerols for fat-based food products: A review. In Food Research, 4(4).398. https://doi.org/10.26656/fr.2017.4(4).398
Tasneem, M., Siddique, F., Ahmad, A., & Farooq, U. (2014). Critical reviews in food science and nutrition stabilizers: indispensable substances in dairy products of high rheology stabilizers: indispensable substances in dairy products of high rheology. Critical Reviews in Food Science and Nutrition, 54(7): 869-879.https://doi.org/10.1080/10408398.2011.614702
Triana, R. N., Andarwulan, N., Affandi, A. R., & Nur, R. C. (2015). karakteristik sensori donat dengan penambahan emulsifier mono-diasilgliserol dari Fully Hydrogenated Palm Stearin.Jurnal Mutu Pangan, 2(1) 34-40. https://journal.ipb.ac.id/index.php/jmpi/article/view/27868
Wilbey, R. A. (2006). Emulsifiers in food technology. International Journal of Dairy Technology, 59(1):52-53. https://doi.org/10.1111/j.1471-0307.2006.00224.x
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