Karakterisasi sifat fisiko kimia pati bengkuang (Pachirrhyzus erosus) dan pati ganyong (Canna edulis Kerr) modifikasi [Characteristization on physico-chemical properties of modified canna (Canna edulis Kerr.) and jicama (Pachirrhyzus erosus) starches]

Sri Haryani Anwar, Yeni Chandra Dewi, Novi Safriani

Abstract


Modification of native starch is needed mainly to increase its solubility in water thus broaden its application in food industries. On the other hand, modification of canna and jicama starches have rarely been applied. Physical and chemical modifications of starches are conducted to modify starch characteristics. The research aimed to investigate the physico-chemical properties of canna and jicama starches that had been modified chemically and physically. Chemical modifications which were conducted included modification via substitution with Octenyl Succinate Anhydride (OSA) and hydrolysis using hydrochloric acid (HCl), while physical modification was conducted via the Heat Moisture Treatment (HMT). The starch physico-chemical characteristics evaluated were degree of acid (DA), swelling power, degree of substitution (DS), moisture, ash, fat, and fiber contents. The analysis results showed that moisture, ash, fat, and fiber contents of native canna and jicama starches were not significantly different from those of modified ones. The result also revealed that the type of starches and modification methods increased the swelling power significantly (P≤0,05). The DS of modified canna dan jicama starches were 0.0246% and 0.0176%, respectively. While the DA of modified canna and jicama starches were 0.14% and 0.18%, respectively. This DA values of modified starches by HCL hydrolysis had meet the Indonesian National Standard (SNI 01-2593-1992) which is maximum of 5% for food application.

Keywords: canna starch, jicama starch, HMT modification, modified starch, OSA modification

 


Keywords


pati bengkuang; pati ganyong; pati modifikasi; modifikasi HMT; modifikasi OSA

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References


Ai, Y., & Jane, J. (2018). Chapter 3—Understanding Starch Structure and Functionality. In M. Sjöö & L. Nilsson (Eds.), Starch in Food (Second Edition) (pp. 151–178). Woodhead Publishing. https://doi.org/10.1016/ B978-0-08-100868-3.00003-2

Amaya-Llano, S. L., Martínez-Bustos, F., Martínez Alegría, A. L., & de Jesús Zazueta-Morales, J. (2011). Comparative studies on some physico-chemical, thermal, morphological, and pasting properties of acid-thinned jicama and maize starches. Food and Bioprocess Technology, 4(1), 48–60. https://doi.org/10.1007/s11947-008-0153-z

Anwar, S. H., Rahmah, M., Safriani, N., Hasni, D., Rohaya, S., & Winarti, C. (2016). Exploration of breadfruit, jicama, and rice starches as stabilizer in food emulsion. International Journal on Advanced Science, Engineering and Information Technology, 6(2), 141–145. https://doi.org/10.18517/ijaseit.6.2.613

Anwar, S. H., Safriani, N., Asmawati, Zainal Abiddin, N. F., & Yusoff, A. (2017). Application of modified breadfruit (Artocarpus altillis) starch by Octenyl Succinic Anhydride (OSA) to stabilize fish and microalgae oil emulsions. International Food Research Journal, 24(6), 2330–2339.

Artati, E. K., & Andik, P. A. (2006). Pengaruh konsentrasi asam terhadap hidrolisis pati pisang. Ekuilibrium, 5(1), 8–12.

Bhosale, R., & Singhal, R. (2006). Process optimization for the synthesis of octenyl succinyl derivative of waxy corn and amaranth starches. Carbohydrate Polymers, 66(4), 521–527. https://doi.org/10.1016/ j.carbpol.2006.04.007

Carolina, A., & Ilmi, F., N. (2016). Production of Indonesian Canna edulis type IV resistant starch through acetylation modification. International Food Research Journal, 23(2), 491–497.

Chen, P., Xie, F., Zhao, L., Qiao, Q., & Liu, X. (2017). Effect of acid hydrolysis on the multi-scale structure change of starch with different amylose content. Food Hydrocolloids, 69, 359–368. https://doi.org/10.1016/j.foodhyd.2017.03.003

Faridah, D. N., Rahayu, W. P., & Apriyadi, M. S. (2013). Modifikasi pati garut (Marantha arundinacea) dengan perlakuan hidrolisis asam dan siklus pemanasan-pendinginan untuk menghasilkan pati resisten tipe 3. Jurnal Teknologi Industri Pertanian, 23(1), 61–69.

Herawati, H., Widiasa, I. N., & Kendriyanto, K. (2012). Modifikasi asam suksinat—Gelombang pendek untuk produksi tapioka suksinat. AgriTECH, 30(4), 223–230. https://doi.org/10.22146/agritech.9712

Hoover, R. (2010). The impact of heat-moisture treatment on molecular structures and properties of starches isolated from different botanical sources. Critical Reviews in Food Science and Nutrition, 50(9), 835–847. https://doi.org/10.1080/10408390903001735

Hustiany, R., Fardiaz, D., Apriyantono, A., & Nun. (2010). Modification of Acylation and Succinylation of Tapioca Starch. Jurnal Teknologi Dan Industri Pangan, 16(3), 206. https://doi.org/10.6066/503

Ismail, B. P. (2017). Ash Content Determination. In S. S. Nielsen (Ed.), Food Analysis Laboratory Manual (pp. 117–119). Springer International Publishing. https://doi.org/10.1007/978-3-319-44127-6_11

Khan, K. H., Ali, T. M., & Hasnain, A. (2014). Effect of chemical modifications on the functional and rheological properties of potato (Solanum tuberosum) starches. J. Anim. Plant Sci., 24(2), 550–555.

Klein, B., Pinto, V. Z., Vanier, N. L., Zavareze, E. da R., Colussi, R., Evangelho, J. A. do, Gutkoski, L. C., & Dias, A. R. G. (2013). Effect of single and dual heat–moisture treatments on properties of rice, cassava, and pinhao starches. Carbohydrate Polymers, 98(2), 1578–1584. https://doi.org/10.1016/j.carbpol.2013.07.036

Li, L., Hong, Y., Gu, Z., Cheng, L., Li, Z., & Li, C. (2018). Effect of a dual modification by hydroxypropylation and acid hydrolysis on the structure and rheological properties of potato starch. Food Hydrocolloids, 77, 825–833. https://doi.org/10.1016/j.foodhyd.2017.11.026

Lin, C.-L., Lin, J.-H., Lin, J.-J., & Chang, Y.-H. (2019). Progressive alterations in crystalline structure of starches during heat-moisture treatment with varying iterations and holding times. International Journal of Biological Macromolecules, 135, 472–480. https://doi.org/10.1016/j.ijbiomac.2019.05.193

Muzaifa, M., Sulaiman, M. I., & Liyuza, D. (2014). Evaluasi sifat fisik pati ganyong (Canna edulis kerr.) sebagai bahan baku pembuatan kwetiaw pada tingkat substitusi yang berbeda. Sagu, 13(2), 35–40.

Pangesti, Y. D., Parnanto, N. H. R., & Ridwan, A. A. (2014). Kajian sifat fisikokimia tepung bengkuang (Pachyrhizus erosus) dimodifikasi secara heat moisture treatment (HMT) dengan variasi suhu. Jurnal Teknosains Pangan, 3(3), 72–77.

Purwani, E. Y., Widaningrum, W., Thahir, R., & Muslich, M. (2016). Effect of heat moisture treatment of sago starch on its noodle quality. Indonesian Journal of Agricultural Science, 7(1), 8–14. https://doi.org/10.21082/ijas.v7n1.2006.p8-14

Putri, A. P., Octari, T., Annisa, N., Gadri, A., & Aprilia, H. (2016). Evaluasi Fisikokimia Pati Canna indica L Modifikasi Esterifikasi dan Hidrolisis Asam. Indonesian Journal of Pharmaceutical Science and Technology, 3(3), 78–82. https://doi.org/10.15416/ijpst.v3i3.9361

Ratnayake, W. S., & Jackson, D. S. (2006). Gelatinization and solubility of corn starch during heating in excess water: New insights. Journal of Agricultural and Food Chemistry, 54(10), 3712–3716. https://doi.org/10.1021/jf0529114

Richana, N., & Sunarti, T. C. (2004). Karakterisasi Sifat Fisikokimia tepung Umbi Dan Tepung Pati Dari Umbi Ganyong, Suweg, Ubikelapa Dan Gembili. Jurnal Penelitian Pascapanen Pertanian, 1(1), 29–37. https://doi.org/10.21082/jpasca.v1n1.2004.29-37

Ritika, B. Y., Khatkar, B. S., & Yadav, B. S. (2010). Physicochemical, Morphological, Thermal and Pasting Properties of Starches Isolated from Rice Cultivars Grown in India. International Journal of Food Properties, 13(6), 1339–1354. https://doi.org/10.1080/10942910903131407

Santoso, B., Pratama, F., Hamzah, B., & Pambayun, R. (2015). Karakteristik fisik dan kimia pati ganyong dan gadung termodifikasi metode ikatan silang. Jurnal Agritech, 35(03), 273. https://doi.org/10.22146/agritech.9337

Sjöö, M., & Nilsson, L. (2017). Starch in Food: Structure, Function and Applications (2nd ed.). Woodhead Publishing.

Standar Nasional Indonesia. (1989). Dekstrin untuk industri non pangan SNI 06-1451-1989. Badan Standarisasi Nasional Indonesia, Jakarta.

Standar Nasional Indonesia. (1992). Dekstrin untuk industri pangan SNI 01-2593-1992. Badan Standarisasi Nasional Indonesia, Jakarta.

Sui, Z., Yao, T., Zhao, Y., Ye, X., Kong, X., & Ai, L. (2015). Effects of heat–moisture treatment reaction conditions on the physicochemical and structural properties of maize starch: Moisture and length of heating. Food Chemistry, 173(April), 1125–1132. https://doi.org/10.1016/j.foodchem.2014.11.021

Sun, Q., Zhu, X., Si, F., & Xiong, L. (2015). Effect of acid hydrolysis combined with heat moisture treatment on structure and physicochemical properties of corn starch. Journal of Food Science and Technology, 52(1), 375–382. https://doi.org/10.1007/s13197-013-0998-7

Sweedman, M. C., Tizzotti, M. J., Schäfer, C., & Gilbert, R. G. (2013). Structure and physicochemical properties of octenyl succinic anhydride modified starches: A review. Carbohydrate Polymers, 92(1), 905–920. https://doi.org/10.1016/j.carbpol.2012.09.040

Syafutri, M. I., Pratama, F., Malahayati, N., & Hamzah, B. (2018). Swelling power and WSI of modified Bangka sago starch. Indian Journal of Natural Products and Resources, 9(1), 66–69.

Syamsir, E., Haryadi, P., Fardiaz, D., Nuri, A., & Kusnandar, F. (2012). Pengaruh Proses Heat-Moisture Treatment (HMT) Terhadap Karakteristik Fisikokimia Pati. Jurnal Teknologi dan Industri Pangan, 23(1), 100–106.

Tan, X., Li, X., Chen, L., Xie, F., Li, L., & Huang, J. (2017). Effect of heat-moisture treatment on multi-scale structures and physicochemical properties of breadfruit starch. Carbohydrate Polymers, 161(April), 286–294. https://doi.org/10.1016/j.carbpol.2017.01.029

Ulbrich, M., Daler, J. M., & Flöter, E. (2020). Acid hydrolysis of corn starch genotypes. II. Impact on functional properties. Food Hydrocolloids, 98, 105249. https://doi.org/10.1016/j.foodhyd.2019.105249

Wahid A.S., N. Richana, dan C. Djamaluddin. 1992. Pengaruh umur panen dan pemupukan terhadap hasil dan kualitas ubi kayu varietas gading dan adira-4. Titian Agronomi. Buletin Penelitian. Agronomi (1), 11–15.

Wang, S., Blazek, J., Gilbert, E., & Copeland, L. (2012). New insights on the mechanism of acid degradation of pea starch. Carbohydrate Polymers, 87(3), 1941–1949. https://doi.org/10.1016/j.carbpol.2011.09.093

Ward, R. E., & Carpenter, C. E. (2010). Traditional Methods for Minerals Analysis. In Food Analysis Laboratory Manual (pp. 201–215). Springer International Publishing. https://doi.org/10.1007/978-3-319-44127-6_11

Zulaidah, A. (2012). Peningkatan nilai guna pati alami melalui proses modifikasi pati. Dinamika Sains, 10(22). https://jurnal.unpand.ac.id/index.php/dinsain/article/view/101




DOI: http://dx.doi.org/10.23960/jtihp.v26i1.25-36

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